Chemical Forums
Chemistry Forums for Students => Inorganic Chemistry Forum => Topic started by: KritikalMass on April 02, 2010, 07:13:03 PM
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Could someone please give me some hints or direct me to some literature that explains how it is that the carbons in carborane can have six bonds? All throughout organic chemistry they kept emphasizing how carbon can never have more than four covalent bonds, but here in carborane the carbons have six bonds. My only hypothesis is that the bonds are not entirely covalent. When I asked my polymer chemistry professor he said that thinking about carborane gave him a headache and he advised me to try to figure it out on my own. Thanks!
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Could someone please give me some hints or direct me to some literature that explains how it is that the carbons in carborane can have six bonds? All throughout organic chemistry they kept emphasizing how carbon can never have more than four covalent bonds, but here in carborane the carbons have six bonds. My only hypothesis is that the bonds are not entirely covalent. When I asked my polymer chemistry professor he said that thinking about carborane gave him a headache and he advised me to try to figure it out on my own. Thanks!
So, I've only taken general chemistry so I don't really know. But could it be half bonds, like the case is with B2H6?
Take a look at this,
http://en.wikipedia.org/wiki/Three-center_two-electron_bond
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So, I've only taken general chemistry so I don't really know. But could it be half bonds, like the case is with B2H6?
That's so funny that you mentioned that because he did kind of try to explain it and that was the exact same molecule he used as an example. He said the boron is "sp3 distorted". He then said that maybe the carbons are doing something similar. I appreciate you're answer, and will definitely check it out, although I do believe that there is a more precise answer.
Thanks for your response :)
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I am not sure at all but the first thing that would come to mind for me is that it was derived from carbenes
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So, I've only taken general chemistry so I don't really know. But could it be half bonds, like the case is with B2H6?
Take a look at this,
http://en.wikipedia.org/wiki/Three-center_two-electron_bond
Yes, that is what it was.
http://www.princeton.edu/~mjjr/1,2-de.html
Thank you.