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μ* in Raoult vs μ* in Henry for Chemical Potential
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Topic: μ* in Raoult vs μ* in Henry for Chemical Potential (Read 1200 times)
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Mercento
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μ* in Raoult vs μ* in Henry for Chemical Potential
«
on:
September 15, 2019, 04:34:35 AM »
I am pulling my hair out.
So for Raoult's law:
μ
i
=μ∗
i
+RTlnx
i
For Henry's law:
μ
B
(T,p)=μ
ref
x,B
(T,p)+RTlnx
B
So my question is, is μ∗
i
= μ
ref
x,B
(T,p) ? Or does one of them mean for when substance is in high concentration (solution) and the other for when substance in low concentration (solute)?
Really appreciate your assistance.
Edit: my reference
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textbook_Maps/DeVoe%27s_%22Thermodynamics_and_Chemistry%22/09%3A_Mixtures/9.4_Liquid_and_Solid_Mixtures_of_Nonelectrolytes#9.4.5___The_ideal-dilute_solution
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μ* in Raoult vs μ* in Henry for Chemical Potential