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Topic: metal complex application~  (Read 6327 times)

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Offline yin323

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metal complex application~
« on: November 10, 2006, 05:23:28 AM »
I am doing a project about the colour in transition metal complex.
But how's it related to our daily life?
I wanna find some application of " the color of transition metal" , which is based on the principle of the ligand exchange of the metal complex.
Could you guys give me some ideas about this topics?
Thanks so much!!!  :)

Offline DevaDevil

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Re: metal complex application~
« Reply #1 on: November 10, 2006, 04:54:38 PM »
Best known example (I think) of the use of changeing colors in transition-metal ions are the Chromium dyes.
Examples:
Cr2O3 - "chrome green"
PbCrO4 - "chrome yellow"
Cr added to Al2O3 makes a ruby red

Offline yin323

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Re: metal complex application~
« Reply #2 on: November 10, 2006, 11:45:28 PM »
Best known example (I think) of the use of changeing colors in transition-metal ions are the Chromium dyes.
Examples:
Cr2O3 - "chrome green"
PbCrO4 - "chrome yellow"
Cr added to Al2O3 makes a ruby red

The example needs to relate to the exchange ligand of transition metal >_<

But anyway, thanks a lot!! :)

Offline FeLiXe

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Re: metal complex application~
« Reply #3 on: November 11, 2006, 04:11:03 PM »
the typical expample is a cobalt complex. it's either pink or blue depending on air humidity.
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Offline mdlhvn

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Re: metal complex application~
« Reply #4 on: November 19, 2006, 09:37:12 AM »
Right, it is a typical example. CoCl2 is used as an indicator, the drying agent is blue when still active, pink when exhausted, corresponding to the anhydrous and hydrated forms of CoCl2, respectively. Cobalt chloride paper is likewise used to detect the presence of water. Here Cl ligands is replaced by water ligands
 

Offline Ψ×Ψ

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Re: metal complex application~
« Reply #5 on: November 22, 2006, 08:23:15 PM »
eriochrome black T!  still used by environmental labs to determine water hardness.

Offline mdlhvn

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Re: metal complex application~
« Reply #6 on: November 27, 2006, 08:59:55 AM »
eriochrome black T!  still used by environmental labs to determine water hardness.
-----------> What do you mean? eriochrome black T! is an indicator

Offline green-goblin

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Re: metal complex application~
« Reply #7 on: November 27, 2006, 10:19:26 AM »
eriochrome black T!  still used by environmental labs to determine water hardness.
-----------> What do you mean? eriochrome black T! is an indicator


It turns red when bound to a metal so can be used detect calcium in water and hence  indicate its hardness

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