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Topic: Identifying the oxides corresponding to the following bases  (Read 4161 times)

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Offline RossMoesis

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Identifying the oxides corresponding to the following bases
« on: September 17, 2006, 04:40:36 AM »
Hello, I'm a chemistry undergrad at the university of oklahoma and in the process of taking advanced inorganic chemistry but I'm struggling with this problem. I need to identify the oxides correspnding to the following bases: 

A- potassium hydroxide
B- Chromium (III) hydroxide, Cr(OH)3     

Plus is there an easy way to identify the changes in oxidation states in these equations?

A-  Mg(s) + FeSO4(aq) --> Fe(s) + MgSO4

B- 2 HNO3(aq) + 3 H2S(aq)  ---> 2 NO(g) + 3 S(s) + 4 H2O(l)


Any help would be greatly appreciated, I have a text next week  :'(

Offline Yggdrasil

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Re: Identifying the oxides corresponding to the following bases
« Reply #1 on: September 17, 2006, 02:41:01 PM »
Plus is there an easy way to identify the changes in oxidation states in these equations?

A-  Mg(s) + FeSO4(aq) --> Fe(s) + MgSO4

B- 2 HNO3(aq) + 3 H2S(aq)  ---> 2 NO(g) + 3 S(s) + 4 H2O(l)

For A, you have to remember two easy rules to determine the oxidation state of metals:
1) the oxidation state of the pure metal is 0
2) the oxidation state of a metal ion is equal to its charge

For B, you can figure out the oxidation states of the N and S by using another set of simple rules (these rules are applicable to redox reactions involving non-metals, the other set of rules are for redox reactions with metals):
1) the oxidation state of oxygen is almost always -2 (exceptions: peroxides and superoxides)
2) the oxidation state of hydrogen is almost always +1 (except when in an ionic compound with a metal)
3) the sum of the oxidation states of the atoms in a molecule is equal to its charge

For example, in HNO3, an uncharged molecule, you know that:

ONH + ONN + 3ONO = 0

where ONH = the oxidation state of H in HNO3
ONN = the oxidation state of N in HNO3, etc.

By rules (1) and (2), we know that ONH = +1 and ONO = -2.  Therefore:

1 + ONN + 3 x (-2) = 0

By simple algebra, you can find ONN = +5

Repeat this process for the other compounds in the reaction to find how the oxidation states change for all atoms involved.

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