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Topic: Annealing of Potassium Chlorate  (Read 1280 times)

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Offline Rafovafo

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Annealing of Potassium Chlorate
« on: March 04, 2021, 03:43:11 PM »
Hi there. First post so I am not sure whether I am doing this right or not, but anyway. I got an assignment from my chemistry teacher and I can't figure out this: Calculate the volume of oxygen after the annealing of 3g of potassium chlorate within the standard conditions. (also please bare with me as English is not my first language so I am not sure whether I am using the correct terms in it, sorry if not)

Offline chenbeier

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Re: Annealing of Potassium Chlorate
« Reply #1 on: March 04, 2021, 04:27:50 PM »
What is your work.

Develop chemical equation potassium chlorate to oxygen
According to the equation look up the ratio of them
Calculate the mole of the 3 g
Convert this to the ratio
Then compute the volume

Offline Rafovafo

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Re: Annealing of Potassium Chlorate
« Reply #2 on: March 04, 2021, 04:33:36 PM »
What is your work.

Develop chemical equation potassium chlorate to oxygen
According to the equation look up the ratio of them
Calculate the mole of the 3 g
Convert this to the ratio
Then compute the volume

Hi, thanks for the answer. Honestly I had no idea how to start this assignment at all. Also, if possible, could you maybe describe what you answered in a bit more detail? Translating this to Croatian doesn't give me the best results, although I do think I know what you meant, and if so I should get this:

2KClO3 (s)  --> 2KCl (s) + 3O2 (g)

M(KCl) = Ar (K) + Ar (Cl) = 74.55

n(KCl) = m/M = 0.0402 mol

n(KCl)/n(O2) = 2/3

(O2) = 3n(KCl)/2

n(O2)=  0.0603 mol

and finally V0m = V0/n = 22.4/0.0603 = 0.0603 = 371.5L
however this seems like a huge amount of gas, what is the mistake in here?

edit:
First of all a friend told me its supposed to me n(KClO3)/n(O2) not n(KCL)
That led me to M(KClO3) = 122.55 and n(O2)=0.036
I also just realized its supposed to be V0m*n = 0.8064
Is that the right answer?

« Last Edit: March 04, 2021, 05:41:32 PM by Rafovafo »

Offline chenbeier

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Re: Annealing of Potassium Chlorate
« Reply #3 on: March 05, 2021, 02:40:09 AM »
0,82 l is right answer.

2 KClO3 ..3 O2
1 KClO3....1.5 O2
3g KClO3  . 0,0245 mol ..0.036 mol O2
0.036 mol ...0.822  l

Offline Borek

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Re: Annealing of Potassium Chlorate
« Reply #4 on: March 05, 2021, 03:07:41 AM »
3 g is the mass of potassium chlorate that decomposed, not produced KCl.

and finally V0m = V0/n = 22.4/0.0603 = 0.0603 = 371.5L

Not sure where you got the formula from, but it is wrong - the volume is directly proportional to the number of moles, so you should multiply, not divide.
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