January 15, 2025, 01:06:58 PM
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Topic: How to predict which conjugate base is stronger without knowing Kb values?  (Read 968 times)

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Offline fruity pebble

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Hi there!  :)
I am stumped on a problem asking me to identify whether HCO3- or CO32- is a stronger conjugate base. I am not given any other information, and I was wondering how this would be possible. I know there is a rule that states the more oxygens are present, the stronger the acid/base, but I don't believe it applies here because there are not any hydrogens present in both of these conjugate bases. The question that comes after this asks whether NO3- or NO2- is stronger, and I also don't know how to approach this one either. Would the rule of more oxygens apply in this scenario? Any help would be greatly appreciated!
Thank you!  :D
« Last Edit: March 21, 2021, 11:08:14 PM by fruity pebble »

Offline Borek

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Is there any relationship between strengths of the acid and its conjugate base?

You are given two bases - can you write their conjugate acids? What do you know about their strengths?
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Offline fruity pebble

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Well I know that the conjugate acid of HCO3- is H2CO3, and I know that the conjugate acid of CO32- is HCO3-, and I believe the Ka's decrease in value after successive losses of the H+ ion, meaning that HCO3- has to have a lower Ka than H2CO3 if I'm not mistaken. A lower Ka would mean a higher Kb, meaning a stronger base. So, the one with a lower Ka would be the stronger base, meaning the conjugate base of HCO3-, which was CO32-. Hopefully my thought process is correct  :)

Offline Borek

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A bit convoluted what you wrote is ;) But yes, looks like you got it right.
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Offline fruity pebble

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Great, thank you for the guidance!  :D

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