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Topic: supramolecules  (Read 3869 times)

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Offline renu

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supramolecules
« on: October 12, 2006, 05:43:14 AM »
hi,wanted to ask out of spherands & corands which would have higher affinity for alkali metal ions & why???kindly describe taking into account pre-organisation & kinetic, thermodynamic selectivity
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Offline swati

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Re: supramolecules
« Reply #1 on: October 12, 2006, 05:50:27 AM »
 ??? I am not sure whether I am correct o not, but spherands are more rigid thus more preorganised, thereby have high binding constant than corands. So spherands should have  high affinity for alkali metals than corands.
Am I correct ?
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