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Chirality of oxygen atom
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Topic: Chirality of oxygen atom (Read 1094 times)
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Shreezy666
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Chirality of oxygen atom
«
on:
January 16, 2022, 12:27:22 PM »
Is it possible for an oxygen atom to be a chiral centre. Since chirality is based on the principle that an atom has four different electron densities around it and nitrogen can also be chiral, I was wondering if this is possible?
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Orcio_87
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Re: Chirality of oxygen atom
«
Reply #1 on:
January 16, 2022, 12:31:40 PM »
If protonated as in your molecule (CH
3
-CH
2
-OH
+
-CH
3
) then yes.
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Shreezy666
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Re: Chirality of oxygen atom
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Reply #2 on:
January 16, 2022, 12:36:34 PM »
Thank you Orcio_87
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Orcio_87
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Re: Chirality of oxygen atom
«
Reply #3 on:
January 16, 2022, 12:44:35 PM »
@Shreezy666
If memory is correct similiar amines - CH
3
-CH
2
-NH-CH
3
undergoes rapid inversion, so they are chiral in theory, but not in practice.
I mean - does this compound can be isolated in practice (as some form of a salt) is the other thing.
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Shreezy666
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Re: Chirality of oxygen atom
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Reply #4 on:
January 16, 2022, 01:06:02 PM »
@Orcio_87
Curious about that myself
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Chirality of oxygen atom