November 23, 2024, 11:39:36 PM
Forum Rules: Read This Before Posting


Topic: Diels-Alder: Exo vs Endo and Matched vs Mismatched  (Read 1172 times)

0 Members and 1 Guest are viewing this topic.

Offline VictorNova

  • Very New Member
  • *
  • Posts: 2
  • Mole Snacks: +0/-0
Diels-Alder: Exo vs Endo and Matched vs Mismatched
« on: April 17, 2023, 05:51:18 PM »
While working on this lab report thing, I came across this issue. I've been having trouble distinguishing between how to draw endo vs exo when drawing organic structures and I don't get what is being asked regarding matched and mismatched. Could anyone help explain it to me?
Here's the problem in question:

Offline spirochete

  • Chemist
  • Full Member
  • *
  • Posts: 547
  • Mole Snacks: +51/-9
  • Gender: Male
Re: Diels-Alder: Exo vs Endo and Matched vs Mismatched
« Reply #1 on: April 20, 2023, 08:26:17 PM »
I am not familar with this term, but maybe mismatched refers to the 1,3 isomer, which is the disfavored constitutional isomer that might form as a minor product? The major product should have a 1,2 relationship between the methoxy group and the ester group in this case.

Sponsored Links