January 15, 2025, 07:59:08 AM
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Topic: Reduction of potassium permanganate  (Read 468 times)

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Offline emma.qmc

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Reduction of potassium permanganate
« on: December 31, 2024, 09:58:27 PM »
So I'm running experiments on catalyzed/uncatalyzed reactions of potassium permanganate with sodium sulfite in basic environment. I saw that the catalysts for this reaction can be iron or cobalt sulfate.

Are any of these catalysts 'better' than the other? Or are there other options?

Thank you!

Offline Hunter2

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Re: Reduction of potassium permanganate
« Reply #1 on: January 01, 2025, 03:31:06 AM »
I think you need no catalyst. The reaction takes place also without catalyst.

Offline emma.qmc

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Re: Reduction of potassium permanganate
« Reply #2 on: January 01, 2025, 07:29:02 PM »
Yes but my experiment is to determine the activation energy between uncatalyzed/catalyzed reactions at different temperatures. Do you think this would be a good reaction to do so? I looked at the iodine clock but I'm afraid I'll mess it up.

Thank you!

Offline Hunter2

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Re: Reduction of potassium permanganate
« Reply #3 on: January 02, 2025, 01:25:13 AM »
I don't think it's a good reaction. What are the products of this reaction.
How do you want to determine the activation energy general and special with this reaction.

Offline emma.qmc

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Re: Reduction of potassium permanganate
« Reply #4 on: January 02, 2025, 12:17:47 PM »
What I'm counting on is the colour change from purple to clear. I'll graph the arrhenius graph and then find the activation energy using the gradient.

Offline Hunter2

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Re: Reduction of potassium permanganate
« Reply #5 on: January 02, 2025, 12:23:52 PM »
Then go back to school and  learn more about manganese.
In alcaline environment  this reaction is not taking place. You will get black precipitate of manganese dioxide.
Mn VII goes to Mn IV.
Colourless you will get only in acidic environment.
Mn VII goes to Mn II

Offline emma.qmc

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Re: Reduction of potassium permanganate
« Reply #6 on: January 02, 2025, 04:15:36 PM »
Oh wait I realized I typed basic, I meant acidic....sorry! But do you think it could work? Again sorry for the typo!

Offline Hunter2

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Re: Reduction of potassium permanganate
« Reply #7 on: January 05, 2025, 08:15:55 AM »
The reaction itself works, but how do you want to get the Arrhenius graph?
If you mix the permanganate  with acid and sulfite it change direct colour.

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