I asked this, because I read something interesting.
Phosphorus pentachloride makes a compound with ammonia, reacting directly and this when heated decomposes, yielding NH3Cl and HCl, and a substance of the formula PNH, with primary alcohols it gives the dialkylamine.
Looks like an interestingly easy synthesis for diethylamine and dimethylamine
What say you people?
*whoops, was that the bottle of lysergic acid I just knocked over...only joking
)