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Topic: Harmonic potential and covalent bonds  (Read 3118 times)

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Offline rfaraday

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Harmonic potential and covalent bonds
« on: February 26, 2007, 05:58:12 PM »
Covalent bonds are often approximated by the harmomic potential
Vbond= Vobond + kbond (r-ro)2
I have to prove that

dvbond/dr =0  for r=r0
dvbond/dr < 0 for r<r0
anddvbond/dr > 0 for r> r0

The derviative is force. So this makes sense. When r = r0 force should be ) b/c it is a minima. Is the question just asking me to take the derviative of the equation given. How would I do that when the different r's are inserted

Thanks

Offline Yggdrasil

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Re: Harmonic potential and covalent bonds
« Reply #1 on: February 26, 2007, 09:08:26 PM »
Step 1: Take the derivative of Vbond(r) with respect to r to obtain an expression for V'bond(r).

Step 2:  Find the sign of V'bond(r) for the indicated values by plugging in values of r into your expression for V'bond(r).

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