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Topic: DIBAH (Read 3830 times)
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derster
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DIBAH
«
on:
May 05, 2007, 10:02:04 PM »
Can someone please provide the major organic product which results when (CH3)2-CH-CH2-CH2-COCl is treated with DIBAH.
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refid
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Re: DIBAH
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Reply #1 on:
May 05, 2007, 11:44:38 PM »
well i know ester become aldehyde when treated with DIBAH... i assume since the acyl chloride is the most reactive, would probably go to the primary alcohol.. just guess
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Dolphinsiu
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Re: DIBAH
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Reply #2 on:
May 06, 2007, 03:53:10 AM »
(CH3)2-CH-CH2-CH2-COCl + DIBAL-H
--> RCOCl + DIBAL (Rewrite)
+
O -
-
Al (i-Bu)2
ll l
--> R - C H
\
Cl
O OH
ll DIBAL-H l
--> R - C - H --> R - C - H
l
H
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