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Topic: Calculating pH of solutions.  (Read 2965 times)

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Offline MrTom

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Calculating pH of solutions.
« on: March 13, 2007, 05:35:06 PM »
Hi all, first post here.

This seems pretty easy, but I came across this question, and wondered how I would go about answering it:

Calculate the pH of the resulting solutions when:

1) 10.0cm3 of 1.0M HCl are added to 990cm3 of water
2) 20.0cm3 of 1.0M NaOH are added to 980cm3 of water.

Thanks alot in advance.

MrTom

Offline Borek

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Re: Calculating pH of solutions.
« Reply #1 on: March 13, 2007, 05:45:12 PM »
1st - out of the pH definition.

2nd - out of the pOH definition (assuming you know what pH+pOH is).

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Offline MrTom

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Re: Calculating pH of solutions.
« Reply #2 on: March 14, 2007, 04:31:31 PM »
Ooh, ofcourse, I feel abit dumb now.
I'm quite new to the topic and I was getting abit 'led astray' by the water in the question, but I got it now;

1) Work out the number of moles of HCl; 0.01dm3 x 1.0M = 0.01 moles HCl, therefore, 0.01 moles H+
pH = -log100.01 = 2

2) Again, work out moles of NaOH (0.02 x 10.M =) 0.02 moles.
pKa = -log100.02 = 1.7
pKa + pKb = 14, so, pKb = 14 - 1.7 = 12.3

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