here molarity = moles, because the volume is 1.00L and hence can be effectively left out of the equation. since we are dealing with gases, the 'volume' of the solution can be taken to be the volume of the container, which is 1.00L.
as for your second question, think about where the reaction will head (excess reagents, but on which side?) and then form an algebraic equation with 'x' as the amount that will react/be produced. fit it into the equilibrium constant and work out the math.