Please read the
Forum Rules[/url]. You must show your attempt at answering the question before we will help you. However, here are some guiding questions:
Do you know how to convert kcal to kJ? How much heat is released when 1 mol of rust is formed?
For the second question, first calculate the heat needed to condense 8.5g of steam at 100
oC into 8.5 g of steam at 100
oC. Then calculate the amount of heat released when the water cools from 100 to 15 degrees.