Dear Baba
The concentration of NH3 as Nitrogen is the same as concentration of NH4Cl as Nitrogen (because just one N is added to the solution).
53,5g NH4Cl (1 mole NH4Cl)have 14g N (one mole of N)
5g x
x = 5*14/53,5(g)
Concentration = x/100 (g/ml)
Good luck,