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Topic: forming precipitates  (Read 6750 times)

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Offline laxplayer

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forming precipitates
« on: October 21, 2007, 03:32:22 PM »
okay, the question says "When the following solutions are mixed together, what precipitate (if any) will form?" and the problem is "Al(NO3)3 (aq) + Ba(OH)2 (aq)"
i got the results to be Al(OH)2 and Ba(NO3)3 and i don't think either of those are a precipitate. I am using the precipitation diagram where it shows the rows of cations and columns of anions. Am I doing anything wrong because when I enter those answers they are incorrect, and when I put "none" it also comes out as incorrect. 

Offline Sev

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Re: forming precipitates
« Reply #1 on: October 21, 2007, 04:21:55 PM »
Quote
i got the results to be Al(OH)2 and Ba(NO3)3 and i don't think either of those are a precipitate.

Aluminium hydroxide is Al(OH)3, Barium nitrate is Ba(NO3)2.  One of these will ppt out of soln.
Hint: nitrates are soluble.

Offline laxplayer

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Re: forming precipitates
« Reply #2 on: October 21, 2007, 04:32:20 PM »
oh, can you explain to me why the subscripts are 3 and 2 rather than what I got?

Offline Mitch

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Re: forming precipitates
« Reply #3 on: October 21, 2007, 04:37:18 PM »
Aluminum has an oxidation state of +3, while hydroxide(-OH) has an oxidation state of -1.
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Offline laxplayer

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Re: forming precipitates
« Reply #4 on: October 21, 2007, 04:43:29 PM »
so is this a redox reaction?

Offline Sev

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Re: forming precipitates
« Reply #5 on: October 21, 2007, 04:53:56 PM »
Quote
so is this a redox reaction?

No, since the oxidation states don't change.

Offline laxplayer

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Re: forming precipitates
« Reply #6 on: October 21, 2007, 05:18:19 PM »
then i still don't get why you change the subscripts

Offline enahs

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Re: forming precipitates
« Reply #7 on: October 21, 2007, 05:24:28 PM »
then i still don't get why you change the subscripts

Aluminum typically carries a 3+ charge. OH- carries a -1 charge. To form the stable precipitate it has to be neutral (no charge). Therefor to make the solution neutral you need 3 OH- for every for every 1 Al3+ ((+3) + (3*(-1)) = 3-3 = 0.


Quick search turned this up, give it a read over:
http://www.chemistry.co.nz/chemequa.htm

Offline laxplayer

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Re: forming precipitates
« Reply #8 on: October 21, 2007, 06:02:29 PM »
i get it now, thanks :]

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