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Topic: Interpreting IRs  (Read 3408 times)

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Offline curiousgeorge1234

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Interpreting IRs
« on: October 24, 2007, 10:49:28 PM »
I have gone to the website http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/direct_frame_top.cgi which has been highly recommended for IRs. 

I have found the compound I need to identify. 

I am trying to determine various bonds, ie. C=O, etc.  I notice there is a box at the bottom of the IR Spec. which has information for specific wavelengths (I assume) but I can't find an index or anything to tell me what the numbers represent.  For example, I see 3600 (which I assume is the wavelength) and then a second number like 44 beside it (not sure what this is).

Anyone familiar with this site?

Offline agrobert

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Re: Interpreting IRs
« Reply #1 on: October 24, 2007, 11:14:36 PM »
The first number (3600) is the wavenumber (frequency) in cm-1 and the next number (40) is relative to the intensity (measured in % Transmittance - converted from absorbance) of the observed peak on a scale from 0-100 from bottom to top.
In the realm of scientific observation, luck is only granted to those who are prepared. -Louis Pasteur

Offline Yarr

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Re: Interpreting IRs
« Reply #2 on: October 26, 2007, 05:19:49 AM »
Check this page for some spectroscopy problems. Basic knowledge of IR spectroscopy is addressed in problems 3,4,7,13,15,18. See also some of the structure determination problems in 20.

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