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Topic: Help, does anyone know where to start?!  (Read 4010 times)

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Offline keishii

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Help, does anyone know where to start?!
« on: November 07, 2007, 10:25:40 AM »
A sample of copper ore of mass 0.4225g was dissolved in acid and the resulting solution of copper(II) reacted with the iodide ion.
2Cu 2+ + 4I - --> 2CuI + I2
The I2 produced required 29.96 cm3 of 0.02100 mol dm-3 Na2S2O3 solution for complete reaction according to the following equation.
2S2O32- + I2 --> S4O62- + 2I-
What was the % by weight of copper in the copper ore?  ???

Offline Borek

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Re: Help, does anyone know where to start?!
« Reply #1 on: November 07, 2007, 11:17:10 AM »
Please read forum rules.

You have to do stoichiometry backwards - how many moles of thiosulfate were used? Which means how much iodine? For that amount of iodine - what was the amount of copper (II)?
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Offline keishii

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Re: Help, does anyone know where to start?!
« Reply #2 on: November 07, 2007, 12:23:35 PM »
Sorry I didn't read the forum rules... :-[

So far for 2S203 2- I have moles = 29.96 x 0.021 = 0.62916/ 1000 = 6.2916 x 10-4
And since the ratio is 2:1 .
6.2916 x 10-4 / 2 = 3.1458 x 10 -4

Then I'm stumped! Would I need to work out the amount in g?

Offline Lozia

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Re: Help, does anyone know where to start?!
« Reply #3 on: November 07, 2007, 01:14:30 PM »
 You x's 3.1458 x 10 -4 by 2 as 2Cu make 1 I2

You then do Moles x Mr (of copper) = Actual amount in grams

Then just do (that/0.4225) x 100

That should give you a percentage.

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