December 22, 2024, 12:35:17 AM
Forum Rules: Read This Before Posting


Topic: clausius-clapeyron - help solving!  (Read 5178 times)

0 Members and 1 Guest are viewing this topic.

Offline orenstrawberrybanana

  • Very New Member
  • *
  • Posts: 1
  • Mole Snacks: +0/-0
clausius-clapeyron - help solving!
« on: November 26, 2007, 11:25:46 PM »
have problem solving this question- i need some help :)

the normal boiling point of benzene is 80.1oC and its triple point lies at 6.85oC and 0.052atm. use the clausius-clapeyron equation to estimate the molar enthalpy of vaporization. given that the molar enthalpy of sublimation of benzene is 44.05kj mol-1, calculate the molar enthalpy of fusion

Offline Hunt

  • Chemist
  • Full Member
  • *
  • Posts: 240
  • Mole Snacks: +25/-7
  • Gender: Male
Re: clausius-clapeyron - help solving!
« Reply #1 on: November 28, 2007, 04:45:18 PM »
you just need to plug in the values. 

Take, Ln P_v = -delta_vap H / RT + C ( constant of integration)

plug in the coordinates of the trip pt and normal boil pt to solve 2 eq's of 2 uknowns . u find delta_vap H. Then ofcourse delta H sublimation = fusion + vaporization. You find the changei n enthalpy of fusion.

Sponsored Links