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Topic: Dissociation constants and pH for bases and acids question.  (Read 6409 times)

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Offline rosco_pk

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Dissociation constants and pH for bases and acids question.
« on: December 12, 2007, 12:46:22 PM »
Hello folks, wondering if you can help with a question that is challenging myself and a couple of classmates.
The question is not homework and wont be needed for our final exam but it is set out in the notes as a Challenge Question and the three of us are having some trouble answering it. We have the answers from the notes and have tried working backwards but to no avail.

Q: Calculate the pH of the solution formed when:
   
    a) 35 cm3M NaOH are added to 50 cm3M ethanoic acid. (Ka = 1.8 x 10-5)
   
    b) 20 cm3M HCL are added to 50 cm3M NH4OH (Kb = 1.8 x 10-5)

Any help would be appreciated and if possible an explanation of how you worked through it. The answers in the notes say a) = 5.11 and b) = 9.1 but having worked through a lot of the questions in the notes quite a few answers are wrong so that could very well be the case here.

Thanks

Rosco
   
P.S. - this is all the information that is given for the question.

Offline Borek

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Offline AWK

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Re: Dissociation constants and pH for bases and acids question.
« Reply #2 on: December 12, 2007, 01:05:36 PM »
Quote
cm3M
What does mean?
Define concentrations of your solutions!
AWK

Offline rosco_pk

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Re: Dissociation constants and pH for bases and acids question.
« Reply #3 on: December 12, 2007, 05:13:49 PM »
Im presuming it means Mols per cm3 but thats exactly as it is written in the question. I cant define it. Thats all the information we are given in the question.

Offline Borek

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Re: Dissociation constants and pH for bases and acids question.
« Reply #4 on: December 12, 2007, 05:55:39 PM »
Quote
cm3M
What does mean?
Define concentrations of your solutions!

Wow, missed this one. No concentrations, no answers.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline AWK

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Re: Dissociation constants and pH for bases and acids question.
« Reply #5 on: December 13, 2007, 01:09:28 AM »
Im presuming it means Mols per cm3 but thats exactly as it is written in the question. I cant define it. Thats all the information we are given in the question.
For calculations you should use a molar concentratiom  1M = 1 mol/dm3
AWK

Offline rosco_pk

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Re: Dissociation constants and pH for bases and acids question.
« Reply #6 on: December 19, 2007, 05:58:33 PM »
Hi thanks for the advice. Our tutor has decided to remove the question from the notes. He deems it unnecessary for the course. Blinking SQA are crap!

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