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Topic: Consecutive Elementary Reactions  (Read 5567 times)

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Offline roxie321

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Consecutive Elementary Reactions
« on: January 27, 2008, 09:17:05 AM »
Hi everyone,
with consecutive elementary reactions A -->I--->P
I'm having trouble integrating from d[ I]/dt = k1[A]0exp(-k1t) - k2[ I]
to
[ I] = (k1/(k2-k1))(exp(-k1t)-exp(-k2t))[A]0

If that wasnt clear then http://staff.um.edu.mt/jgri1/teaching/che2372/notes/08/01/elementary_rxns.html
shows the equations nicely. If anyone could help it would be greatly appreciated.

Offline Yggdrasil

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Re: Consecutive Elementary Reactions
« Reply #1 on: January 27, 2008, 11:54:14 AM »
If you have a 1st order linear differential equation that cannot be solved by separation of variables, you can use the integrating factor method:

http://en.wikipedia.org/wiki/Integrating_factor

Let us know if this helps.

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