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Topic: Entropy problems  (Read 5157 times)

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Offline Joules23

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Entropy problems
« on: March 28, 2008, 07:09:41 PM »


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#1) Consider the following reaction at 298 K.
2 SO2(g) + O2(g) -->  2 SO3(g)

An equilibrium mixture contains O2(g) and SO3(g) at partial pressures of 0.31 atm and 2.9 atm, respectively. Using data from Appendix 4, determine the equilibrium partial pressure of SO2 in the mixture.
  atm

My attempt:
First calculat DG, which = -142KJ
Then use: DG = -RTlnK, to find K
-142 = (-8.314E-3)(298)(lnK)
K=7.78

7.78= (2.9^2/(.31X^2))
X= SO2 = 1.87atm
*****
« Last Edit: March 30, 2008, 12:44:06 PM by Joules23 »

Offline Yggdrasil

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Re: Entropy problems
« Reply #1 on: March 30, 2008, 02:59:50 PM »
For figuring out the equilibrium partial pressure, you need to make an ICE table.  At equilibrium you will not have 2.9atm of SO3 because some will react to form more O2 and SO2.

Offline Joules23

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Re: Entropy problems
« Reply #2 on: March 30, 2008, 03:28:13 PM »
but in the problem it says "An equilibrium mixture contains O2(g) and SO3(g) at partial pressures ..."
So i thought that meant it is already at equilibrium..

Offline Yggdrasil

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Re: Entropy problems
« Reply #3 on: March 30, 2008, 03:49:36 PM »
Ah, you are correct.  When I calculate K I get 7.78x1024.  Maybe that is your problem.

Offline Joules23

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Re: Entropy problems
« Reply #4 on: March 30, 2008, 04:07:41 PM »
i dunno how i missed that lol, thanks!

Offline champ

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Re: Entropy problems
« Reply #5 on: March 30, 2008, 04:46:28 PM »
check your units.. convert "Kj" to "J" and then u will find the right ans. for "k". lol

Offline Joules23

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Re: Entropy problems
« Reply #6 on: March 30, 2008, 04:53:18 PM »
No, my units are fine, the KiloJoules (or joules) cancel out, K has no units.. its just i guess when i glanced at my calulator i missed the E24 part

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