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Topic: thiosemicarbazide solution  (Read 3204 times)

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Offline BRZI

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thiosemicarbazide solution
« on: April 29, 2008, 10:08:23 AM »
I have problem with dissolution of thiosemicarbazide in ethanol. I tried to dissolute a thiosemicarbazide in ethanol but it seems that thiosemicarbazide is slightly solubile in ethanol. also i heated an ethanol but also nothing. does ethanol solution of thiosemicarbazide means thiosemicarbazide hydrochloride?? I need to react a thiosemicarbazide with diketone (benzil) in ethanol solution.

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Offline movies

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Re: thiosemicarbazide solution
« Reply #1 on: April 29, 2008, 01:54:11 PM »
Have you tried adding some water?  That helps a lot with semicarbazide, but I have never used thiosemicarbazide.

If you are using the hydrochloride salt you may need to add a base to get it to got into solution.  Something like pyridine or sodium acetate usually works.

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