November 28, 2024, 11:33:40 PM
Forum Rules: Read This Before Posting


Topic: Reaction of Aluminium, Phosphorus & Sulphur?  (Read 4387 times)

0 Members and 1 Guest are viewing this topic.

Offline D4rr3n

  • Regular Member
  • ***
  • Posts: 15
  • Mole Snacks: +0/-0
Reaction of Aluminium, Phosphorus & Sulphur?
« on: May 13, 2008, 12:54:04 PM »
If powder aluminium + Phosphorus + Sulphur were mixed together and heated what would be the resulting compound? Would it be AlP + S


Thanks for any help


Offline DevaDevil

  • Chemist
  • Full Member
  • *
  • Posts: 690
  • Mole Snacks: +55/-9
  • Gender: Male
  • postdoc at ANL
Re: Reaction of Aluminium, Phosphorus & Sulphur?
« Reply #1 on: May 13, 2008, 02:10:40 PM »
if you would heat them in inert atmosphere (Argon for example) I would expect phospherous sulfides, PxSy (sorry no idea what the coefficients may be) Aluminium Sulfide Al2S3 and aluminium phosphide AlP to be possible products.

if you heat them in air, all would form oxides.

Offline D4rr3n

  • Regular Member
  • ***
  • Posts: 15
  • Mole Snacks: +0/-0
Re: Reaction of Aluminium, Phosphorus & Sulphur?
« Reply #2 on: May 13, 2008, 03:49:46 PM »
I guess this would be quite a nasty mix, dangerous/harmful to preform?


Offline DevaDevil

  • Chemist
  • Full Member
  • *
  • Posts: 690
  • Mole Snacks: +55/-9
  • Gender: Male
  • postdoc at ANL
Re: Reaction of Aluminium, Phosphorus & Sulphur?
« Reply #3 on: May 16, 2008, 04:57:24 PM »
yes.

aside from tricky as you don't want to expose it to air or water (the sulfide/phosphide compounds will hydrolize easily) they will form for example toxic H2S when exposed to water
Aluminum phosphide is a pesticide, and thus toxic.

Better not to perform any of this unless you know what you are doing, and doing it properly and safely.

Sponsored Links