When an atom decays by positron emission the atomic number goes down by 1 so an electron will be lost reducing the mass.
Technically a positron is lost and while the mass (amu) is reduced, the mass number does not change.
When an atom decays by electron emission the atomic number goes up by 1 so an electron will be gained increasing the mass.
There is a difference between electron emission and electron capture. During electron emission an electron is lost not gained and once again the mass number does not change.
Both types of decay are internal conversions in which a neutron is converted into a proton, or a proton is converted into a neutron. However, while Z changes, the number of neutrons is adjusted accordingly and the mass number stays the same.
In the case where there is neutron excess in the nucleus you have electron emission
0n
1 —>
+1p
1 + e
- (Total mass number before and after is 1)
In the case where there is an excess of protons in the nucleus you have positron emission
1p
1 —>
0n
1 + e
+Both processes involve the release of neutrinos, which are necessary because of conservation of angular momentum.
While electrons are easier to detect, positrons (beta +) are a little more difficult. They almost instantaneously combine with an electron to produce a photon, which has an energy equal to 1.02 MeV
Recall that the mass of a neutron is sightly larger than that of a proton. Thus, relativistically one can see that the loss of mass from a neutron to a proton is part of the mass and energy of the electron given off.
However, for the conversion from a proton into a neutron there has to be an increase in mass (not for the isotope) in addition to the mass of the positron being emitted, since the mass of the neutron is slighlty larger than that of a proton.
Both processes are nuclear processes which means that they do not occur with the free particles. The energetics depend on the interactions between all the nucleons.
So, to answer the question the energy available for beta - decay (e - ) is given by:
Q
B- = M(A, Z) - M (A, Z + 1) Thus, the energy available is equal to the difference in the neutral atomic masses.
For the case of beta + decay (e + )
Q
B+ = M(A, Z) - M (A, Z + 1) - 2m0 Where m0 is the rest mass of the electron. Positron emission is energetically forbidden when the mass difference between parent and product neutral atoms is less than 2 m 0 or in energy terms 1.02 MeV.