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Topic: V([V(O)(H2O)5]SO4 + H2O  (Read 5048 times)

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Offline Dolphinsiu

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V([V(O)(H2O)5]SO4 + H2O
« on: May 02, 2008, 10:20:57 AM »
[V(O)(H2O)5]SO4 is d1 complex as V(0) is d5 complex. Six coordination of this complex, giving rise to 12 electrons, is hence coordinatively unsaturated. V(IV) is a very high oxidation state. Hence it is electron-deficient metal center so that H2O in [V(O)(H2O)5]2+ is highly acidic. Upon addition of water, deprotonation of metal complex exists with release of proton.

[V(O)(H2O)5]2+ + H2O --> [V(O)(H2O)4(OH)] + + H3O+

In above reaction, HSO4- is the counter ion for the product.

[V(O)(H2O)4(OH)] + + H2O --> [V(O)(H2O)3(OH)2] + H3O+

[V(O)(H2O)3(OH)2] + + H2O --> H[V(O)(H2O)2(OH)3]
--> H2[V(O)(H2O)1(OH)4] --> H3[V(O)(OH)5]

Am I correct?
« Last Edit: May 02, 2008, 10:31:48 AM by Dolphinsiu »

Offline KhemistKen

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Re: V([V(O)(H2O)5]SO4 + H2O
« Reply #1 on: June 20, 2008, 11:20:52 AM »
I would expect that a small portion of the vanadium would react as in your first equation.  Wouldn't expect any significant contribution from the other reactions however.

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