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Topic: electrocyclic reaction  (Read 2926 times)

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Offline Lithium

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electrocyclic reaction
« on: July 25, 2008, 11:41:16 AM »
Can someone tell me the major product of 2E,4E,6E-octa-2,4,6-triene and halogen light?  Can this reaction occur?   I know its going to form a cyclohexane with two methyl i just need to know the sterochemistry cis or trans.  I know you have to use 4n+2 since it has 6 pie electrons.  I was informed by a classmate this couldnt happen.  is he correct if not what is the answer

Offline azmanam

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Re: electrocyclic reaction
« Reply #1 on: July 25, 2008, 12:43:10 PM »
as written, the reaction will not occur.  the ends of the pi system cannot overlap to undergo the electrocyclization.
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Offline azmanam

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Re: electrocyclic reaction
« Reply #2 on: July 25, 2008, 01:57:49 PM »
(and if it did cyclize, it would not form a cyclohexane)
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