Some time ago, billnotgatez was trying to solve a problem of how to combine two ethanols by dehydration into a butanol at room temperature. The problem seemed hopelessly intractabe, to say the least.
Here recently, I read some info about research by Professor Gabriele Centi from the University of Messina in Italy. It involves binding carbon atoms together into hydrocarbon chains of up to eight or nine carbon atoms long using platinum and palladium catalysts inside carbon nanotubes. The process has one percent efficiency at room temperature. But this is already two to three times greater efficiency than any other industrial process.
I was wondering if this method of catalysis (or something similar) could potentially synthesize butanol and other larger hydrocarbons such as gasoline from simple alcohols like methanol and ethanol...at room temperature as well. Although the reaction rates would be somewhat slow.
I've noticed that some people here in these forums are not very informed or "up-to-date" on all the developments taking place in the field of microwave catalyzed reactions these days. Overall energy transferrence is indeed a more important factor for specific molecules at specific frequencies than threshold energy of individual photon quanta as expressed by the formula E = hv. Man-made radio waves are radically different from most natural electromagnetic energy. It is all one great big seamless wave of energy and has nothing to do with individual photon quanta...rendering false interpretation of physical science and quantum dogma surrounding E = hv unconsequential and totally useless for man-made radio waves. In fact, the good ol' fashioned Newtonian model better explains man-made radio phenomena.
Which brings me to the next possible idea: almost all molecules and chemical substances have a so-called specific "radio resonance" frequency. If the right compatible frequencies can be found for these platinum and palladium catalysts inside carbon nanotubes...then the reaction rates of simple alcohols into larger molecules of butanol and gasoline may be greatly accelerated...at temperatures just slightly higher than room temperature ( because some amount of thermal transfer will still take place in addition to reactions...even at ideal frequency applied).
I would like to see Professor Gabriele Centi or some other researcher try performing this experiment in the near future to see how well this method of ethanol dehydration dimerisation is capable of working. It might not be workable if the radio energy applied also does some sort of reactive damage to the carbon nanotube structures as well. This will require experimentation with highly selective frequencies to determine what works best and to try and prevent this from happening. I also hope that billnotgatez reads this and finds it to be of some interest.