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Topic: Equilibrium problem  (Read 8061 times)

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Offline calmwater3000

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Equilibrium problem
« on: October 02, 2008, 04:30:55 PM »
Hi,
I have been trying to figure this problem out myself and I'm not getting the same answer as the one in my book.

The question:

A 2.50 mole quantity of NOCl was initially in a 1.50-L reaction chamber at 400 Celsius. After equilibrium was established, it was found that 28.0 percent of the NOCl had dissociated:

2NOCl(gas) <--> 2NO(gas) + Cl2(gas)

The equation would be- K= [NO]^2[Cl]/[NOCl]^2

2.50 / 1.50 L= 1.67 m/L of initial concentration of NOCl

1.67 m/L * .28 = 0.467 , 1.67 - 0.467 = 1.2 m/L amount of concentration at equilibrium for NOCl,

My question is how do I calculate the equilibrium concentration for NO and Cl2?

Offline Borek

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Re: Equilibrium problem
« Reply #1 on: October 02, 2008, 04:53:03 PM »
Stoichiometry.
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Offline calmwater3000

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Re: Equilibrium problem
« Reply #2 on: October 02, 2008, 05:16:02 PM »
I don't get how stochiometry apply to this,
So 1.2 m/L of NOCl multiply by 2 = 2.4 m/L of NOCl, NO2 would also be 2.4 m/L and Cl2 would be 1.2 m/L?

If I work this out, K= [2.4^2][1.2]/[2.4^2] then K would be 1.2 which wouldn't be the right answer, the text book have an answer of 3.53x10-2

Offline Borek

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Re: Equilibrium problem
« Reply #3 on: October 02, 2008, 05:51:18 PM »
Take a look at the reaction equation. You know that 28% of 2.5 moles NOCl dissociated - how many moles of NO were produced?
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Offline calmwater3000

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Re: Equilibrium problem
« Reply #4 on: October 02, 2008, 06:41:14 PM »
Ok, I know what you meant now. I got the same answer as the one in the textbook, thanks!  :)

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