To solve this problem, we need de-construct the data provided into solvable simultaneous equations.
A compuond of chlorine and fluorine, CIFx, reacts at about 75 degrees C with uranium to produce uranium hexafluoride and chlrine fluoride, CIF.
This is an unbalanced equation: ClF
x + U -> UF
6 + ClF
We have to balance it first: ClF
x + y.U -> y.UF
6 + ClF
=> x = 6y + 1
=> we need 1 more independent equation to solve this problem.
A certain amount of uranium produced 5.63 g of uranium hexafluroide and 457 mL of chlorine fluoride at 75 degrees C and 3.00 atm.
This data here would provide us the means to calculate the various mole ratio of reactant to reactant and reactant to product. This mole ratio would be the source of our 2nd independent equation.
molar mass of UF
6 = 238.03 + 6*19.00 = 352.03 g/mol
number of moles of UF
6 formed = mass / (molar mass) = 5.63 / 352.03 = 0.01599 = 0.016 moles
assuming perfect gas,
number of moles of ClF formed = (P*V)/ (R*T) = (3.03975*10
5 Pa * 0.000457 m
3) / (8.314 J.mol
-1.K
-1 * 348 K) = 0.048 moles
Given that the molar ratio of UF
6 to ClF is y:1, then
y = (number of moles of UF
6 formed) / (number of moles of ClF formed) = 0.016/0.048 = 1/3
x = 6y + 1 = 3
Describe the geometry, polarity, and bond angles, of the compound and the hybridization of chlorine. How many sigma and pi bonds are there.
Don't forget to consider the lone pairs and the bonding pair of electrons on Chlorine's valence shell to evaluate the state of Chlorine's hybridisation.