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Topic: How to prepare [Co(NH3)6]2(CO3)2  (Read 3896 times)

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Offline sanya86

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How to prepare [Co(NH3)6]2(CO3)2
« on: May 24, 2010, 11:21:36 AM »
Hi!
I need to prepare this compound so if anyone knows how please tell me.
Thanks
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Offline AWK

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Re: How to prepare [Co(NH3)6]2(CO3)2
« Reply #1 on: May 25, 2010, 03:01:24 AM »
Do you really mean Co(IV) ?
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Offline sanya86

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Re: How to prepare [Co(NH3)6]2(CO3)2
« Reply #2 on: May 25, 2010, 09:14:16 AM »
Sorry my mistake
 [Co(NH3)6]2(CO3)3
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Offline AWK

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Re: How to prepare [Co(NH3)6]2(CO3)2
« Reply #3 on: May 25, 2010, 11:13:47 AM »
It seems to be extremely difficult since cobalt easily form stable chelate complex of type [Co(NH3)4CO3]+
though structure of [Co(NH3)6]ClCO3 is reported
Z. Naturforsch. 56 b, 1117–1122 (2001);
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