Dear pauljohn;
In a certain number of cases you can only add some monomer (of same or other kind) to grow the chains; or you add a bi-functional monomer to stick oligomers together. So you have also the possibility to design mixed polymer chains to control their phys. properties.
Think about: Each polymer has to start, when the first two monomers link/stick together, so also two different monomers (not of all kind) can start to link.
Good Luck!
ARGOS++