December 03, 2024, 12:24:06 PM
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Topic: Isopulegon  (Read 4788 times)

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Offline Jetsam

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Isopulegon
« on: October 17, 2024, 01:30:37 AM »
Hello. Can you look at my mechanic reaction of isopulegon from citronellol?
I dont know how to write a proton transfer and i dont know the rest is correct

Offline rolnor

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Re: Isopulegon
« Reply #1 on: October 17, 2024, 03:45:33 AM »
There seems to be a lot of pages on the web that describes the synthesis.


https://www.researchgate.net/figure/Mechanism-of-Citronellal-Cyclization-Tursiloadi-et-al-2015_fig5_353602161

Offline galonch1

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Re: Isopulegon
« Reply #2 on: Today at 03:12:30 AM »
I'm having a hard time understanding this alcohol oxidation. I know that adding PCC to the primary alcohol will produce an aldehyde, but I'm not sure how it becomes cyclic. I originally thought that it was the OCOCH3-, but the formation of isopulegone from PCC alone has me confused.

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