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Topic: equilibrium constant (Read 6051 times)
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Ice-cream
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equilibrium constant
«
on:
June 15, 2005, 09:33:48 AM »
for equilibrium constants, when K<1, the reactants are favoured, when K>1 the products are favoured and when K=1...what happens?
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angelguy
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Re:equilibrium constant
«
Reply #1 on:
June 15, 2005, 09:40:42 AM »
It means that the gibbs energy change between the reactant and the product is zero. Which is why k =1 as in del G = -RTlnK.
Thanks,
angelguy
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Juan R.
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Re:equilibrium constant
«
Reply #2 on:
June 16, 2005, 04:02:47 AM »
For
A <--> B
in the concentration approx.
K = C
B
/C
A
for K = 1, C
B
= C
A
. There is not preference between reactants and products. Both are equally "stable".
An "trivial" example is ammonia inversion
H \
A = H - N:
H /
/ H
B = :N - H
\ H
«
Last Edit: June 16, 2005, 04:08:22 AM by Juan R.
»
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equilibrium constant