January 15, 2025, 10:36:45 AM
Forum Rules: Read This Before Posting


Topic: Equilibrium Conc. tricky question  (Read 3877 times)

0 Members and 1 Guest are viewing this topic.

Offline Star

  • New Member
  • **
  • Posts: 4
  • Mole Snacks: +0/-0
Equilibrium Conc. tricky question
« on: June 03, 2009, 01:06:31 PM »
I've had enuff >.<    this dam question i cant seem to figure it out and ive tried every different thing i can think of soo far so if anyone else here can show me how to work it out itd b much appreciated :}

at 25 degrees C,   Kc = 0.145 for the reaction in the solvent CCl4:  2BrCl  ::equil:: Br2 + Cl2    IF the initial concentrations of each substance in a solution are 0.0400M - determine the equilibrium concentrations of each substance

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27897
  • Mole Snacks: +1816/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Equilibrium Conc. tricky question
« Reply #1 on: June 03, 2009, 02:22:46 PM »
Show you work so far.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline Gargamel

  • Regular Member
  • ***
  • Posts: 26
  • Mole Snacks: +0/-2
  • Gender: Male
Re: Equilibrium Conc. tricky question
« Reply #2 on: June 03, 2009, 04:01:54 PM »
Try this
                2BrCl        ::equil::      Br2      +        Cl2
Start          0,04M                 0,04M           0,04M
End            0,04M-2x             0,04M+x       0,04M+x

Every time we use 2 mole of BrCl we get 1 mole of Br and 1 mole of Cl and vice versa.

Find x by using the equilibrum law, and I think you can figure out the rest.

Offline Star

  • New Member
  • **
  • Posts: 4
  • Mole Snacks: +0/-0
Re: Equilibrium Conc. tricky question
« Reply #3 on: June 03, 2009, 08:46:09 PM »
ok wat i did was work out that Qc was = 1.0  therefore Qc>Kc  (1.0>0.145) sooo   >.<  i thought it meant i use up products therefore BrCl:   0.0400 + 2x ?  and Cl2 = 0.04 - x ? no?
in any case i ended up with    Kc = (0.4 -x)^2/(0.04 + 2x)^2  = 0.145      (im gonna take another stab at it now  >.< )

Offline Gargamel

  • Regular Member
  • ***
  • Posts: 26
  • Mole Snacks: +0/-2
  • Gender: Male
Re: Equilibrium Conc. tricky question
« Reply #4 on: June 04, 2009, 07:00:35 AM »
Oh I'm so sorry if I confused you. You got it right! (forgot the stoichometric coefficient before BrCl so my Q was 0,04. But it is 1 as you say).

Just find x in your equation and insert in

[BrCl] = 0,04 + 2x
[Br2] = [Cl2] = 0,04 - x

Hope this help

Sponsored Links