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Topic: Electro-chemistry: redox reaction of combustion of graphite  (Read 4947 times)

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Offline Noff

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Electro-chemistry: redox reaction of combustion of graphite
« on: January 30, 2010, 09:42:50 PM »
I have a question where I'm supposed to re-write the equation of the combustion of graphite explicitly showing the transfer of electrons:
C (graphite) + O2  ::equil:: CO2
How do I show the transfer of electrons? there don't seem to be any charged species.

Next, I have to find the electromotive force of this cell, E0cell. I could use the equation E = E0 - RT/|v|F * ln Q but then ln Q comes to equal 1 since all the components are pure or in a non-solvent state.

Offline Borek

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Re: Electro-chemistry: redox reaction of combustion of graphite
« Reply #1 on: January 31, 2010, 03:38:07 AM »
Just becasue there are no charged species doesn't mean there was no electron transfer. NaCl is not charged yet charge separation between atoms is obvious.

It is not that obvious in CO2, but still carbon has been oxidized and oxygen has been reduced.

As for E0 - perhaps you should use delta G?
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Offline Schrödinger

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Re: Electro-chemistry: redox reaction of combustion of graphite
« Reply #2 on: January 31, 2010, 04:34:43 AM »
C (graphite) + O2  ::equil:: CO2
How do I show the transfer of electrons? there don't seem to be any charged species.

You wont be able to see any charge species as long as you think of the molecule as a whole. You must look at what happens to every atom.
Hint : oxidation states
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