Sulphur has got to be the worst possible element to use for this kind of question.
For 0.25 mole - yes, for 22 g - no.
So, the are 1.505535375 x 10 23 atoms in 0.250 mole of sulfur?
Watch your siginificant digits, but yes.
If it is right... Depends. As DrCMS stated, this is bad selection of element. Elemental sulfur contains ring shaped sulfur molecules S
8, but this fact is usually ignored. So, if you ignroe this fact - your answer is correct. If you don't ignore this fact - there will be 8 times more atoms than you have calculated. What you have to do is to read mind of your teacher and to guess what s/he expects.
Is it the same if you are looking for molecules, just replace "atoms" with "molecules" ?
See earlier post by MrTeo.