I dont really understand. Ive never done Taylor's theorem (wil learn about it at the end of this semester in my maths course) so maybe thats why I dont understand it?
But please, could someone explain it to me? Here are what my notes say
Virial equation of state and virial coefficients:
Taylor’s theorem: For a function f(x) which has n+1 continuous
derivatives,
f(x) = f(0) +f(0)’x + [f(0)’’/2!] x2 +…[f(0)(n)/n!] xn…
Virial equation of state :
Consider : Z = f(p) at a constant T and n
Apply Taylor theorem to Z = f(p), note that Z -> 1 if p -> 0
Z = 1 + B’p + C’ p2 +…
Or Vm/Vm0 = pVm/RT = (1 + B’ p + C’ p2 +…)
Or p Vm = RT (1 + B’ p + C’ p2 + …) …..(1)
Or p Vm = RT (1 + B/Vm + C /Vm2 + …) …..(2)
(1) and (2) are called the virial equation of state. The coefficients (B’, C’…) and (B, C….) are called virial coefficients; they are functions of T and gas molecules.