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Topic: Helmholtz Energy (A) question  (Read 2736 times)

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Offline G O D I V A

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Helmholtz Energy (A) question
« on: October 20, 2009, 05:46:15 AM »
So my book says that (1) if dA < 0 its spontaneous irreversible, and dA = 0 is reversible (equilibrium).

Now it says that (2) for R-->P if dA < 0 the process occurs spontaneously in forward direction and dA>0 spontaneously in reverse direction. 

I dont understand that.  How does the gas constant become pressure.  How come there is no dA > 0 for (1).

Offline Yggdrasil

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Re: Helmholtz Energy (A) question
« Reply #1 on: October 20, 2009, 11:41:08 AM »
I think R --> P means reactant --> product.

In any case, for a system at constant volume, ΔA < 0 means the process occurs spontaneously in the forward direction, ΔA > 0 means the process occurs spontaneously in the reverse direction, and ΔA = 0 means that the reaction is in equilibrium.

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