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What are the products of these reactions?
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Topic: What are the products of these reactions? (Read 3935 times)
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IoanaD
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What are the products of these reactions?
«
on:
November 04, 2009, 03:23:07 AM »
Both of these reactions take place in the presence of an acid catalyst. For the second reaction I believe we get a cyclical compound like cyclic acetal (except instead of one of the oxygens there's a sulfur). Correct me if I'm wrong,
For the first reaction I'm kind of stuck... I'd really appreciate some enlightenment :S
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orgoclear
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Re: What are the products of these reactions?
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Reply #1 on:
November 04, 2009, 03:25:27 AM »
for the first one, think about cleavage of the ester.
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azmanam
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Re: What are the products of these reactions?
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Reply #2 on:
November 04, 2009, 06:06:30 AM »
the first one isn't an ester, it's a hemiacetal. Think of what happens to hemiacetals under the reaction conditions
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IoanaD
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Re: What are the products of these reactions?
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Reply #3 on:
November 04, 2009, 09:51:14 AM »
AH! i don't know how i could miss that..hemiacetals react with an alcohol in the presence of an acid catalyst to produce an acetal! Ok, thanks for the eye-opener. I had the lecture on this today...
Is this correct for the second one?
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orgopete
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Re: What are the products of these reactions?
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Reply #4 on:
November 04, 2009, 10:36:41 AM »
Yes, and if you apply the same mechanism to the first one, you should arrive at the correct answer for it as well. Hint, you are half-way there.
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IoanaD
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Re: What are the products of these reactions?
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Reply #5 on:
November 04, 2009, 08:50:15 PM »
So the first one would be something like this...i'm sorry, i've just begun working with these reactions.
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Scatter
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Re: What are the products of these reactions?
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Reply #6 on:
November 04, 2009, 08:59:29 PM »
Don't apologize, you're doing great!
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What are the products of these reactions?