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Topic: Pressure calculation  (Read 2744 times)

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Offline Hemidol

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Pressure calculation
« on: November 16, 2009, 11:50:19 PM »
The compound NF3 has van der Waals constants a = 3.580 atm•L2/mol2 and b = 0.0545 L/mol. Using both the ideal gas law and van der Waals’s equation, calculate the pressure expected for 18 mol of NF3 gas in a 6.00-L container at 30 °C.


Not sure how to approach. Any help appreciated.

Offline renge ishyo

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Re: Pressure calculation
« Reply #1 on: November 17, 2009, 01:23:46 AM »
Plug the data into the appropriate formula and solve for P.

For the ideal gas law, use:

PV = nRT

For the Van der Waal's Equation, use:

(P + (n2a)/V2)(V-nb) = nRT

Offline Hemidol

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Re: Pressure calculation
« Reply #2 on: November 29, 2009, 06:37:01 PM »


= 3.580 (18/6.00)^2 * 6 - 0.0545*18
= 161.71218 



(P x a(n/V)2)(V - bn) = nRT is what I used

thus:


P = nRT / V
= 161.71218 / 6.00
=26.95atm

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