From Wikipedia: "When fresh garlic is chopped or crushed, the enzyme alliinase converts alliin into allicin, which is responsible for the aroma of fresh garlic. Allicin and other thiosulfinates in garlic are unstable and form a number of other compounds, such as diallyl sulfide (DAS), diallyl disulfide (DADS) and diallyl trisulfide (DAT), dithiins and ajoene.[2]". and "Allicin features the thiosulfinate functional group, R-S-(O)-S-R." I seem to recall other compounds also, but I don't recall what they were.