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Topic: TCCA to NaDCIC  (Read 3936 times)

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Offline jmarjorie

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TCCA to NaDCIC
« on: July 04, 2005, 07:14:40 AM »
Hi everybody,

Is there any simple way in the lab to convert Tri Chloro isoCyanuric Acid (TCCA) to its lesser derivative Sodium DiChloro IsoCyanuric acid (NaDCIC) ?
This will involve the removal of 1 atom of chlorine and the addition of sodium in its place. It's baffled me.
Thanks in advance,
jmarjorie
 
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Offline movies

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Re:TCCA to NaDCIC
« Reply #1 on: July 05, 2005, 04:34:33 PM »
You might be able to do it with Na0, but it's probably be messy.

Possibly also with something like NaHMDS.

Maybe also try reducing with n-Bu3SnH to form the dichloro compound and then just deprotonate.
« Last Edit: July 05, 2005, 04:35:56 PM by movies »
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Nucleophile

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Re:TCCA to NaDCIC
« Reply #2 on: July 08, 2005, 02:00:54 PM »
urm, basically what Mr. Movies said, take the dichloro compound, deprotonate with NaOH.

Btw, how fair is to call thi-chloro compund an acid - after all, it isn't a Bronsted acid anymore.
« Last Edit: July 08, 2005, 02:01:52 PM by Nucleophile »
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