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Topic: Molecular geometry.  (Read 2676 times)

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Offline vhpk

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Molecular geometry.
« on: January 25, 2010, 08:43:59 AM »
Hi everyone,
I have a question regarding the geometry of the molecule.
Why does the electron pair locate at the equatorial position in AXaE5-a(such as: ClF3, SF4) molecule but at axial equation at AXaE6-a compound(such as: IF52- ? I suppose the reason lies in the reduction in repulsion but still haven't gotten any reasonable explanation?
Thank you for the help.
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Offline Schrödinger

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Re: Molecular geometry.
« Reply #1 on: January 25, 2010, 08:57:36 AM »
The reason is to reduce repulsion.

Hint : Think in terms of bond angles, and how it could possibly affect the interactions between electron pairs placed at the vertices of the geometrical figure under consideration.
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