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Topic: is this 2 isomer of dimethylcyclopropane optically active ?  (Read 5975 times)

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Offline sahar58

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is this 2 isomer of dimethylcyclopropane optically active ?
« on: January 27, 2010, 02:15:15 AM »
is equal mixture of cis-1,2-dimethyl cyclopropane and trans-1,2-dimethyl cyclopropane optically active?


i know that cis-1,2-dimethyl cyclopropane is achiral and is not optically active but what will happen if have equal mixture with trans-1,2-dimethyl cyclopropane?

and what about equal mixture of S,S-trans-1,2-dimethyl cyclopropane and R,R-trans-1,2-dimethyl cyclopropane?

they are enantiomer, so can rotate polrized plane but in opposite direction. is my statement correct?


Offline AWK

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Re: is this 2 isomer of dimethylcyclopropane optically active ?
« Reply #1 on: January 27, 2010, 10:40:05 AM »
Hint: racemate
AWK

Offline sahar58

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Re: is this 2 isomer of dimethylcyclopropane optically active ?
« Reply #2 on: January 28, 2010, 12:47:51 AM »
Hint: racemate

az i know racemate, is one that has equal amounts of left- and right-handed enantiomers of a chiral molecule.

but this 2 conformation are not enantiomers and cis isomer is not chiral, too.

i guess that this mixture has optical activity, because of chiral trans.
?

Offline AWK

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Re: is this 2 isomer of dimethylcyclopropane optically active ?
« Reply #3 on: January 28, 2010, 02:44:30 AM »
Mixture of trans isomers forms a racemate (default). Otherwise you should specify isomer RR or SS.
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