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Topic: Freezing point depression problem  (Read 5027 times)

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Offline cabaal

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Freezing point depression problem
« on: February 23, 2010, 05:57:44 PM »
The freezing point of a solvent is 178.4 °C and the cryoscopic constant is 37.7 °C*kg/mol. How many grams of solute (whose molar mass is 128.2 g/mol) should be mixed with 11.8 g of solvent to lower the freezing point to 169.5 °C?

178.4 °C - 169.5 °C = 8.9 °C Δt.
Kf*m=Δt ==> (37.7 °C*kg/mol)(m)=8.9 °C ==> m = 4.2 mol/kg
4.2 mol/kg = x moles solute/(11.8 g solvent * 1 kg/1000g) ==> x = 0.050 mol solute
0.050 mol solute * 128.2 g/mol = 6.4 g solute

Am I doing anything wrong? My answer was marked incorrect but I can't find any mistakes in my math. Thank you.

Offline Borek

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Re: Freezing point depression problem
« Reply #1 on: February 23, 2010, 06:09:59 PM »
(37.7 °C*kg/mol)(m)=8.9 °C ==> m = 4.2 mol/kg

Really?
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Offline cabaal

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Re: Freezing point depression problem
« Reply #2 on: February 23, 2010, 06:16:00 PM »
(37.7 °C*kg/mol)(m)=8.9 °C ==> m = 4.2 mol/kg

Really?

Oops, that should be 4.2 kg/mol shouldn't it?

Offline Borek

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Re: Freezing point depression problem
« Reply #3 on: February 23, 2010, 06:39:42 PM »
Stop guessing, calculate.
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Offline cabaal

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Re: Freezing point depression problem
« Reply #4 on: February 23, 2010, 06:40:32 PM »
Oh wait...wow how did I even make a mistake so large? That's horrible.  :o

Offline cabaal

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Re: Freezing point depression problem
« Reply #5 on: February 23, 2010, 06:43:35 PM »
Kf*m=Δt ==> (37.7 °C*kg/mol)(m)=8.9 °C ==> m = 0.24 mol/kg
0.24 mol/kg = x moles solute/(11.8 g solvent * 1 kg/1000g) ==> x = 0.0028 mol solute
0.0028 mol solute * 128.2 g/mol = 0.36 g solute

I have absolutely no idea how I made such a stupid mistake.  :-[ Thank you for your help, Borek.

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