November 23, 2024, 08:38:38 PM
Forum Rules: Read This Before Posting


« previous next »
Pages: [1]   Go Down

Topic: hydroxalamine reactivity.  (Read 3761 times)

0 Members and 1 Guest are viewing this topic.

Offline 408

  • Chemist
  • Full Member
  • *
  • Posts: 796
  • Mole Snacks: +103/-30
hydroxalamine reactivity.
« on: May 03, 2010, 07:37:23 AM »
I know hydroxylamine hydrochloride will react with acetonitrile under basic conditions, ie where free hydroxylamine is present, but is it safe to recrystallize a hydroxylammonium salt from acetonitrile?

Thanks, the internet has not been illuminating regarding hydroxylamine reactions under neutral conditions.
Logged

Offline OC pro

  • Chemist
  • Full Member
  • *
  • Posts: 396
  • Mole Snacks: +36/-15
  • Gender: Male
Re: hydroxalamine reactivity.
« Reply #1 on: May 03, 2010, 11:48:44 AM »
100% sure no reactivity. It´s safe to recrystallize it from acetonitrile. I would use methanol.
Logged

Offline 408

  • Chemist
  • Full Member
  • *
  • Posts: 796
  • Mole Snacks: +103/-30
Re: hydroxalamine reactivity.
« Reply #2 on: May 03, 2010, 02:09:11 PM »
too soluble in MeOH.  Another of my salts is of very similar polarity so I anticipate it to work in a similar manner.

Question in a similar vane....acetone, neutral conditions, hydroxylamine hydrochloride; unreactive as well?

Thanks again.
Logged

Offline OC pro

  • Chemist
  • Full Member
  • *
  • Posts: 396
  • Mole Snacks: +36/-15
  • Gender: Male
Re: hydroxalamine reactivity.
« Reply #3 on: May 04, 2010, 07:01:42 AM »
Yeah...the same. Unreactive. You can also try 1,4-dioxane.
Logged
Pages: [1]   Go Up
« previous next »
Sponsored Links