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Topic: Pericyclic reactions  (Read 2563 times)

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Offline chiddler

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Pericyclic reactions
« on: June 03, 2010, 02:49:29 AM »
Hello fellow chemists and, like myself, chemist wannabes. I would really like assistance understanding pericyclic reactions.

My professor told us a rhyme..."when heat is on, 4e is con". I do not understand how to apply con/disrotary rotations to a reaction. Fodder to exemplify this can be one of my homework questions:

How should the orbitals be drawn in HOMO and LUMO? I would really appreciate an answer to this first along with any information you have patience enough to include that may help me.

Thanks very much!

Offline Dan

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Re: Pericyclic reactions
« Reply #1 on: June 03, 2010, 07:23:42 AM »
I highly recommend you get these out of the library:

Frontier orbitals and organic chemical reactions - Ian Fleming
Pericyclic reactions (Oxford chemistry primer) - Ian Fleming
My research: Google Scholar and Researchgate

Offline chiddler

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Re: Pericyclic reactions
« Reply #2 on: June 03, 2010, 01:20:09 PM »
Thanks I found it in the catalog; I will take a look at it.

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